›› 2016, Vol. 37 ›› Issue (S2): 279-286.doi: 10.16285/j.rsm.2016.S2.034

• 基础理论与实验研究 • 上一篇    下一篇

磷酸镁水泥固化铅污染土的力学特性试验研究及微观机制

张亭亭,李江山,王 平,黄 茜,薛 强   

  1. 中国科学院武汉岩土力学研究所 岩土力学与工程国家重点实验室,湖北 武汉 430071
  • 收稿日期:2016-04-20 出版日期:2016-11-11 发布日期:2018-06-09
  • 作者简介:张亭亭,男,1990年生,博士研究生,主要从事污染土多相体作用效应与修复技术方面的研究工作。
  • 基金资助:
    国家自然科学基金(No. 51479194);中国科学院学科交叉与合作创新团队项目(No.Y426011C01);岩土力学与工程国家重点实验室资助课题(No. Z015003)。

Experimental study of mechanical and microstructure properties of magnesium phosphate cement treated lead contaminated soils

ZHANG Ting-ting, LI Jiang-shan, WANG Ping, HUANG Qian, XUE Qiang   

  1. State Key Laboratory of Geomechanics and Geotechnical Engineering, Institute of Rock and Soil Mechanics, Chinese Academy of Sciences, Wuhan, Hubei 430071, China
  • Received:2016-04-20 Online:2016-11-11 Published:2018-06-09
  • Supported by:
    This work was supported by the Chinese National Natural Science Foundation(51479194), Cross-disciplinary Collaborative Teams Program for Science, Technology and Innovation, Chinese Academy of Sciences (Y426011C01), and Project Supported by the State Key Laboratory of Geomechanics, and Geotechnical Engineering(Z015003).

摘要: 采用磷酸镁水泥(MPC)对铅污染土进行固化/稳定化处理。基于无侧限抗压强度试验和渗透试验,研究了MPC添加量、水土比对固化污染土强度及渗透特性的影响规律。结果表明,固化土的强度随MPC添加量增加而增大,渗透系数减小;水土比对固化土的强度及渗透特性的影响均存在临界值,为0.45。低于临界值时,固化土的强度随着水土比的增加而增加,渗透系数随着水土比的增加而减小。压汞试验(MTP)结果表明,随MPC添加量的增大,固化土孔隙体积减小,水土比不超过临界值时,固化土孔隙体积随着水土比的增大而减小。扫描电镜试验结果表明,随着MPC添加量的增加,土颗粒团聚化越明显,胶结程度加强;水土比不超过临界值时,土颗粒团聚体增多。镁钾磷酸盐晶体(MKP)主要通过减少孔径大于1 ?m的孔隙体积来影响固化土的强度和渗透特性。

关键词: 固化/稳定化, 磷酸镁水泥(MPC), 铅污染土, 无侧限抗压强度, 渗透系数, 微观结构

Abstract: Magnesium phosphate cement(MPC) is used to stabilize/solidify lead-contaminated soils. Unconfined compressive strength test and permeability test are conducted to investigate the variation of mechanical properties of MPC treated lead-contaminated soils along with MPC dosage and water content. Results show that the unconfined compressive strength increased significantly with MPC dosage, while the hydraulic conductivity changed oppositely. There is a threshold value for water content of 0.45 of its influence on unconfined compressive strength and hydraulic conductivity. The unconfined compressive strength increased with the water content before the threshold value, while the hydraulic conductivity changed oppositely. “MTP” test results show that the total void volume reduce as the MPC dosage, the total void volume of soil reduce as the water content before the threshold value. SEM test results show that a larger aggregation formation, with a smaller void space in soils as the MPC dosage increase, more obvious aggregation and cementation occur in soils space as the water content less than the threshold value. These results can be attributed to the decreases of the pore volume of soil pores, which the diameter larger than 1 ?m.

Key words: solidification/stabilization(S/S), magnesium phosphate cement(MPC), lead contaminated soil, unconfined compressive strength, hydraulic conductivity, microstructure

中图分类号: 

  • TU 443
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