岩土力学 ›› 2020, Vol. 41 ›› Issue (6): 1944-1952.doi: 10.16285/j.rsm.2019.0647

• 基础理论与实验研究 • 上一篇    下一篇

基于Pitzer离子模型的盐渍非饱和土孔隙 相对湿度计算

文伟1, 2,赖远明1, 2,尤哲敏1,李积锋3   

  1. 1. 中国科学院西北生态环境资源研究院 冻土工程国家重点实验室,甘肃 兰州 730000; 2. 中国科学院大学,北京 100049;3.青海水利水电勘测设计研究院,青海 西宁 810008
  • 收稿日期:2019-04-08 修回日期:2019-10-31 出版日期:2020-06-11 发布日期:2020-08-02
  • 作者简介:文伟,男,1990年生,博士研究生,主要从事旱区半干旱地区盐渍土理论及数值计算方面的研究
  • 基金资助:
    国家重点研发计划重点专项项目(No.2018YFC0809605);中国科学院前沿科学重点研究项目(No.QYZDY-SSW-DQC015);国家自然科学青年基金(No.41601074)。

Analysis of pore relative humidity of salinized unsaturated soil based on Pitzer model

WEN Wei1, 2, LAI Yuan-ming1, 2, YOU Zhe-min1, LI Ji-feng3   

  1. 1. State Key Laboratory of Frozen Soil Engineering, Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou, Gansu 730000, China; 2. University of Chinese Academy of Sciences, Beijing 100049, China; 3. Qinghai Water Conservancy and Hydroelectric Survey and Design Institute, Xining, Qinghai, 810008, China
  • Received:2019-04-08 Revised:2019-10-31 Online:2020-06-11 Published:2020-08-02
  • Contact: 赖远明,男,1962年生,博士,研究员,博士生导师,主要从事寒旱区工程理论和数值分析方面的研究。E-mail: ymlai@lzb.ac.cn E-mail:wwen@lzb.ac.cn
  • Supported by:
    This work was supported by the National Key Research and Development Program of China(2018YFC0809605), the Key Research Program of Frontier Sciences of Chinese Academy of Sciences(QYZDY-SSW-DQC015) and the Young Scientists Fund of the National Natural Science Foundation of China(41601074).

摘要: 在干旱半干旱地区由于土体蒸发速率大而引发的盐渍化会对相关区域范围内的工程构筑物耐久性构成潜在威胁。因此,准确预测土体孔隙相对湿度对于指导工程构筑物防盐具有重要意义。基于土体孔隙水化学势与孔隙气体始终处于平衡状态这一结论,根据化学平衡原理推导了土体孔隙相对湿度计算式。通过与测得的盐溶液空气相对湿度进行对比,结果表明:不同温度不同浓度下的相对湿度计算值与试验值吻合程度高,并且优于R&S计算模型,尤其在溶液中溶质浓度处于近饱和状态时其吻合效果更为明显。同时,在不改变计算参数的前提下,将计算得到的孔隙相对湿度表达式代入到已有数值模型中,经比较发现:计算结果与试验结果吻合程度高,尤其在蒸发速率和体积含水量的预测上。综上所述,新提出的非饱和盐渍土孔隙相对湿度计算式在水盐迁移计算过程中是有效的。

关键词: 非饱和土, 盐渍土, 相对湿度, 水盐迁移

Abstract: In arid and semi-arid regions, salinization caused by high evaporation rate of soil will pose a potential threat to the durability of engineering structures. Therefore, accurate prediction of soil pores relative humidity is of great significance for guiding salt control of engineering structures. Based on the conclusion that the chemical potential of soil pores water is always in equilibrium with pores vapors, a relative humidity expression of unsaturated saline soil pores is deduced according to the principle of chemical equilibrium. By comparing the relative humidity of calculated and the measured solutions, the results can be obtained that the calculated values of relative humidity at different temperatures and concentrations are in good agreement with the experimental values, and are superior to that by the R&S model; the coincidence effect is more obvious especially when the concentration of solute is nearly saturated. Meanwhile, it is found that the numerical results are in good agreement with the experimental results by substituting the proposed relative humidity expression into the existing numerical model without changing the calculation parameters, especially in the prediction of evaporation rate and volume water content. In conclusion, the new formula for calculating pore relative humidity of unsaturated saline soil is effective in the process of water-salt migration calculation.

Key words: unsaturated soil, salinized soil, relative humidity, water-salt migration

中图分类号: TU448
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