Rock and Soil Mechanics ›› 2021, Vol. 42 ›› Issue (8): 2089-2098.doi: 10.16285/j.rsm.2021.0018

• Fundamental Theroy and Experimental Research • Previous Articles     Next Articles

Influencing factors and mechanism analysis of strength development of geopolymer stabilized sludge

ZHOU Heng-yu1, WANG Xiu-shan1, HU Xing-xing2, XIONG Zhi-qi3, ZHANG Xiao-yuan1   

  1. 1. School of Civil Engineering and Architecture, Zhejiang Sci-Tec University, Hangzhou, Zhejiang 310018, China; 2. Zhejiang Titan Design & Engineering Co., Ltd, Hangzhou, Zhejiang 310012, China; 3. China United Engineering Corporation Limited, Hangzhou, Zhejiang 310052, China
  • Received:2021-01-05 Revised:2021-04-15 Online:2021-08-11 Published:2021-08-16
  • Supported by:
    This work was supported by the National Natural Science Foundation of China (51578508), the Natural Science Foundation of Zhejiang Province (LQ19E080025) and the Basic Public Welfare Research Project of Zhejiang Province (LGF18E080015).

Abstract: To solve the problem of carbon emission and high energy consumption of traditional binder, the coal-bearing metakaolin (CMK) geopolymer was used to stabilize sludge. The unconfined compressive strength (UCS) test was conducted to determine the proportion of alkali activator firstly. On this basis, the effects of alkali-precursor ratio, precursor content, NaOH molarity, curing time, curing temperature and slag content on the mechanical properties of stabilized sludge were investigated. Finally, the SEM and XRD tests were conducted to analyse the microstructure of stabilized sludge. The results showed that the UCS of stabilized sludge first increased and then decreased with increasing Na2SiO3:NaOH ratio and the rational proportion of alkali activator of geopolymer was Na2SiO3:NaOH=75:25. The UCS increased as the alkali-precursor ratio, precursor content and NaOH molarity increased. As the curing time, curing temperature and slag content increased, the UCS of stabilized sludge improved more obviously. The microstructural analysis showed that no new minerals were formed in geopolymer stabilized sludge. With the increase of alkali-precursor ratio, precursor content, NaOH molarity, curing time, curing temperature and slag content, the amount of amorphous N-A-S-H and C-(A)-S-H gels increased, which made the soil structure denser through bonding and filling effects, thus increasing the strength of stabilized sludge.

Key words: coal-bearing metakaolin, geopolymer, sludge, mechanical properties, microstructure

CLC Number: 

  • TU 447
[1] ZHI Bin, WEI Yuan-jun, WANG Pan, ZHANG Qian, LIU Cun-li, REN Hui-ming, . Correlation mechanism between macroscopic strength and microstructure of undisturbed loess containing Na2SO4 salt under freeze-thaw cycles [J]. Rock and Soil Mechanics, 2025, 46(S1): 106-120.
[2] WU Jun, MIN Yi-fan, ZHENG Xi-yao, HAN Chen, NIU Fu-jun, ZHU Bao-lin, . Compressive deformation properties of recycled fine aggregates prepared by geopolymer-stabilized sludge method [J]. Rock and Soil Mechanics, 2025, 46(S1): 159-170.
[3] ZHANG Xing-wen, CAO Jing, LEI Shu-yu, LI Yu-hong, CHENG Yun, ZHANG Ning-rui. Effect of fulvic acid environment on the structure and permeability of cement-soil containing humic acid [J]. Rock and Soil Mechanics, 2025, 46(S1): 249-261.
[4] ZHANG Chun-rui, JI Hong-guang, FU Zhen, ZHANG Yue-zheng, SONG Yu, TIAN Zhu-hua, FAN Wen-bo, . Influence of dolomite on the physical and mechanical properties of siltstone [J]. Rock and Soil Mechanics, 2025, 46(9): 2661-2675.
[5] LAI Zhi-qiang, BAI Sheng-yuan, CHEN Lin, ZOU Wei-lie, XU Shu-ling, ZHAO Lian-jun, . Experimental study of dewatering characteristics of ring-type tube stockyard sludge storage [J]. Rock and Soil Mechanics, 2025, 46(9): 2805-2815.
[6] QU Jun-tong, SHI Qi-zhuang, GUO Ying-jie, ZHANG Xiang, LIU Yi, JIANG De-yang. Characteristics and damage mechanisms of ice deposits under freeze-thaw cycles [J]. Rock and Soil Mechanics, 2025, 46(9): 2859-2872.
[7] ZHANG Pei-sen, WANG Hong-wei, HONG Huang, XU Da-qiang, CHEN Zeng-bao, DENG Yun-chi, LIANG Zhan, LI Jin-kun, CHEN Wen-hao, CUI Qian, . Mechanical properties and energy evolution law of deep-buried sandstone under seepage-mining stress coupling [J]. Rock and Soil Mechanics, 2025, 46(7): 1997-2010.
[8] LIU Wen-lin, E Tian-long, FENG Yang-zhou, NIU Song-ying, ZHANG Zi-tang, SUN Yi, CHEN Hong-xin, . Basic properties and freeze-thaw durability of nano-modified geopolymer cutoff wall materials [J]. Rock and Soil Mechanics, 2025, 46(7): 2039-2048.
[9] TAN Yun-zhi, WU Xian-qiao, WU Jun, MING Hua-jun, WANG Chong, XIAO Yu, . Physical and mechanical properties of solidified sludge regulation with phosphogypsum-based aggregate [J]. Rock and Soil Mechanics, 2025, 46(6): 1667-1677.
[10] ZHENG Shu-wen, LIU Song-yu, LI Di, TONG Li-yuan, WU Kai, . Experimental study on mechanical properties of expansive soil-based lightweight foam soil [J]. Rock and Soil Mechanics, 2025, 46(5): 1455-1465.
[11] SONG Yong-jun, LU Yun-long, WANG Shuang-long, XIE Li-jun, CAO Jing-hui, AN Xu-chen, . Evolution characteristics of unfrozen water content and its influence on mechanical properties of rock during freeze-thaw process [J]. Rock and Soil Mechanics, 2025, 46(4): 1049-1059.
[12] ZHANG Tao-yi, WANG Jia-quan, LIN Zhi-nan, TANG Yi, . Influences of fines content on strength deterioration and static shear characteristics of gravelly soil subgrade [J]. Rock and Soil Mechanics, 2025, 46(4): 1141-1152.
[13] TANG Xian-xi, ZHANG Xu-jun, LI Hao-jie, . Evaluation of mechanical properties and analysis of solidification principles of loess solidified with steel slag-coal gangue geopolymer [J]. Rock and Soil Mechanics, 2025, 46(4): 1205-1214.
[14] XUE Qin-pei, CHEN Hong-xin, FENG Shi-jin, LIU Xiao-xuan, XIE Wei, . Evolution of permeability characteristics and micro-mechanism of geopolymer cutoff wall materials under dry-wet cycling [J]. Rock and Soil Mechanics, 2025, 46(3): 811-820.
[15] JIANG Xin-yu, ZHENG Xi-yao, WU Jun, YANG Ai-wu, LI Bo, . Acid resistance performance of geopolymer-stabilized soft clay under HNO3 and H2SO4 acid erosion [J]. Rock and Soil Mechanics, 2025, 46(3): 851-866.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!