岩土力学 ›› 2023, Vol. 44 ›› Issue (1): 43-53.doi: 10.16285/j.rsm.2022.0252

• 基础理论与实验研究 • 上一篇    下一篇

纤维加筋高钙地聚物固化高黏尾砂的 强度特性及机制分析

李源1, 2, 3, 4,魏明俐1, 3, 5,刘磊1, 3, 4, 6,威巍1, 2,陈亿军1, 3, 6   

  1. 1. 中国科学院武汉岩土力学研究所 岩土力学与工程国家重点实验室,湖北 武汉 430071;2. 中国科学院大学,北京 100049; 3. 中国科学院武汉岩土力学研究所 污染泥土科学与工程湖北省重点实验室,湖北 武汉 430071; 4. 中国科学院武汉岩土力学研究所-香港理工大学固体废弃物科学联合实验室,湖北 武汉 430071; 5. 江苏中宜生态土研究院有限公司,江苏 宜兴 214200;6. 武汉中科固废资源产业技术研究院有限公司,湖北 武汉 430070
  • 收稿日期:2022-03-04 接受日期:2022-04-02 出版日期:2023-01-16 发布日期:2023-01-12
  • 通讯作者: 刘磊,男,1982年生,博士,研究员,主要从事固体废弃物安全处置方面的研究工作。E-mail: lliu@whrsm.ac.cn E-mail:liyuan18@mails.ucas.ac.cn
  • 作者简介:李源,男,1996年生,博士研究生,主要从事环境岩土方面的研究工作。
  • 基金资助:
    国家自然科学基金重大科研仪器研制项目(No. 51827814);内蒙古自治区科技重大项目(No. E139320101);湖北省杰出青年基金 (No. 2021CFA096)。

Strength characteristics and mechanism analysis of fiber reinforced highly cohesive tailings solidified using high-calcium geopolymer

LI Yuan1, 2,3, 4, WEI Ming-li1, 3, 5, LIU Lei1, 3,4,6, WEI Wei1, 2 , CHEN Yi-jun1, 3, 6   

  1. 1. State Key Laboratory of Geomechanics and Geotechnical Engineering, Institute of Rock and Soil Mechanics, Chinese Academy of Sciences, Wuhan, Hubei 430071, China; 2. University of Chinese Academy of Sciences, Beijing 100049, China; 3. Hubei Province Key Laboratory of Contaminated Sludge and Soil Science and Engineering, Institute of Rock and Soil Mechanics, Chinese Academy of Sciences, Wuhan, Hubei 430071, China; 4. IRSM-CAS/HK Poly. Univ. Joint Laboratory on Solid Waste Science, Wuhan, Hubei 430071, China; 5. Jiangsu Institute of Zoneco Co., Ltd., Yixing, Jiangsu 214200, China; 6. Wuhan CAS-ITRI Solid Waste Resources Co., Ltd., Wuhan, Hubei 430070, China
  • Received:2022-03-04 Accepted:2022-04-02 Online:2023-01-16 Published:2023-01-12
  • Supported by:
    This work was supported by the Special Fund for Basic Research on Scientific Instruments of the National Natural Science Foundation of China (51827814); the Major Science and Technology Project of Inner Mongolia Autonomous Region (No. E139320101) and the Foundation for Distinguished Young Scholars of Hubei Province (2021CFA096).

摘要: 高黏尾砂固化处理是其资源化利用的重要手段之一。以高黏铁尾砂为对象,开展了高钙地聚物固化尾砂的强度特性试验,分析了玄武岩纤维掺量和干湿循环对固化体强度的影响。围绕固化体的微观胶结行为、无侧限抗压强度、干湿侵蚀响应参数(强度、质量损失、电化学指标)展开讨论,试验发现:(1)纤维加筋增大了强度,0.5%为最优掺量(强度提升29.1%),相当于降低约2%的固化剂用量;(2)纤维−水化产物−尾砂以胶结和摩擦咬合作用相结合,适量纤维导致颗粒间产生微细孔隙,微孔隙的存在增加了持水能力;(3)干湿循环破坏胶结作用,6级循环后达到稳定,纤维对提升固化体抗干湿性不显著。以上成果为弄清固化尾砂强度演化机制及耐久性提供了理论支撑和方法借鉴。

关键词: 高黏铁尾砂, 短切玄武岩纤维, 高钙地聚物, 微观胶结行为, 干湿循环

Abstract: Solidification treatment of highly cohesive tailings is one of the important means for resource utilization. Highly cohesive iron tailings were taken as the object to carry out strength characteristic experiments of solidified tailings using high-calcium geopolymer to analyze the impacts of different dosages of chopped basalt fiber and dry-wet cycles. The micro-cementation behavior, unconfined compressive strength, and the response parameters after dry-wet cycles (strength, mass loss, and electrochemical properties) of the fiber-reinforced solidified materials were discussed. It is concluded that: 1) Adding fiber increased the strength. 0.5% was the optimal dosage (strength increased by 29.1%), which is equivalent to reducing the dosage of geopolymer by about 2%. 2) Fiber, hydration products and tailings were bonded by cementation and frictional occlusion. An appropriate amount of fiber could reduce pore connectivity and increase the capillary water holding capacity. 3) The dry-wet cycles destroyed the cementation, and the damage was stable after the sixth cycle. The fiber has no obvious advantage in improving the dry-wet durability of the solidified materials. The above results provide theoretical support and method reference for clarifying the strength characteristics and durability of solidified tailings.

Key words: highly cohesive iron tailings, chopped basalt fiber, high-calcium geopolymer, micro-cementation behavior, dry-wet cycles

中图分类号: TU 411
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