岩土力学 ›› 2019, Vol. 40 ›› Issue (12): 4652-4658.doi: 10.16285/j.rsm.2017.0803

• 基础理论与实验研究 • 上一篇    下一篇

FeSO4稳定铬污染土的铬赋存形态及浸出特性研究

张亭亭1, 2, 3，李江山1, 4，薛强1, 4，王平1, 4，熊欢5，梁仕华6   

  1. 1. 中国科学院武汉岩土力学研究所 岩土力学与工程国家重点实验室，湖北 武汉 430071；2. 中冶南方都市环保工程技术股份有限公司，湖北 武汉 430205；3. 中国科学院大学，北京 100049；4. 中国科学院武汉岩土力学研究所 污染泥土科学与工程湖北省重点实验室，湖北 武汉 430071；5. 沈阳工业大学 建筑与土木工程学院，辽宁 沈阳 110870；6. 广东工业大学 土木与交通工程学院，广东 广州 510006
  • 收稿日期:2018-04-26 出版日期:2019-12-11 发布日期:2020-01-03
  • 作者简介:张亭亭，男，1990年生，博士研究生，主要从事污染土多相体作用效应与修复技术方面的研究工作
  • 基金资助:
    国家自然科学基金（No.41602315，No.51479194）；湖北省自然科学基金重点项目（No.2016CFA082）；湖北省技术创新专项重大项目（No.2017ACA092）

Chromium speciation and leaching behaviors of hexavalent chromium contaminated soil stabilized by FeSO4

ZHANG Ting-Ting1, 2, 3, LI Jiang-Shan1, 4, XUE Qiang1, 4, WANG Ping1, 4, XIONG Huan5, LIANG Shi-hua6   

  1. 1. State Key Laboratory of Geomechanics and Geotechnical Engineering, Institute of Rock and Soil Mechanics, Chinese Academy of Sciences, Wuhan, Hubei 430071, China; 2. WISDRI City Environment Protection Engineering Limited Company, Wuhan, Hubei 430205, China; 3. University of Chinese Academy of Sciences, Beijing 100049, China; 4. Hubei Key Laboratory of Contaminated Clay Science & Engineering, Institute of Rock and Soil Mechanics, Chinese Academy of Sciences, Wuhan, Hubei 430071, China; 5. School of Architecture and Civil Engineering, Shenyang University of Technology, Shenyang, Liaoning 110870, China; 6. School of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou, Guangdong 510006, China
  • Received:2018-04-26 Online:2019-12-11 Published:2020-01-03
  • Supported by:
    This work was supported by the National Natural Science Foundation of China(41602315, 51479194), the Key Program of Hubei National Natural Science Foundation(2016CFA082) and the Technology Innovation Major Project of Hubei Province(2017ACA092).

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摘要： 采用硫酸亚铁（FeSO4）对Cr(VI)污染土进行稳定化处理。研究了Fe(II)/Cr(VI)摩尔比和养护龄期对污染土稳定过程中的铬赋存形态及浸出特性的影响规律。结果表明：随着Fe(II)/Cr(VI)摩尔比和养护龄期的增加，Cr(VI)和总Cr的浸出浓度降低，稳定土中Cr(VI)的含量降低，当摩尔比为3时，Cr(VI)和总Cr的浸出浓度均低于我国《危险废弃物鉴别标准 浸出毒性鉴别》（GB/T50853―2007）的限值；当摩尔比为10时，稳定土中Cr(VI)的含量低于我国《土壤环境质量标准》（GB15618―2008）中工业和商业用地的限值（30 mg/kg）；当摩尔比为20时，低于居住用地限值（5 mg/kg）。形态提取试验结果表明：FeSO4改变稳定土中铬的赋存形态，可促使铬从弱酸态向可还原态和可氧化态转化，而对残渣态的铬影响不大。Cr(VI)的浸出浓度与稳定土中的Cr(VI)含量均存在指数函数关系，且浸出试验不能全面、客观地评价铬污染土稳定效果。

关键词: 铬污染土, 稳定化, 浸出特性, 硫酸亚铁, 形态演化

Abstract: Ferrous sulfate(FeSO4)was used to stabilize chromium-contaminated soils. Leaching test, alkaline digestion test and sequential extractions test were conducted to investigate the variation of chromium speciation and leaching properties of FeSO4 treated chromium-contaminated soils along with Fe(Ⅱ)/Cr(VI) molar ratio and curing time. Results showed that the leaching concentration(hexavalent chromium and total chromium) and hexavalent chromium content of the soil were decreased significantly with Fe(Ⅱ)/Cr(VI) molar ratio and curing time. When Fe(Ⅱ)/Cr(VI) molar ratio was 3, the Cr(VI) and total Cr leaching concentrations were lower than the identification standards for hazardous wastes: identification for extraction toxicity(GB/T5085.3—2007) of China. Furthermore, When Fe(Ⅱ)/Cr(VI) molar ratio was 10, the amount of Cr(VI) in soil was below the threshold allowed by Environmental quality standards for soils(GB15618—2008) for industrial and commercial reuse of China (Cr(VI)<30 mg/kg). And the civil reuse of soil (Cr(VI)<5 mg/kg) was only achieved with Fe(Ⅱ) /Cr(VI) molar ratio of 20. Sequential extraction procedures revealed that majority of acid soluble fraction of chromium was converted to reducible fraction with FeSO4 stabilized. The leaching concentration of Cr(VI) increased as exponential function with the amount of Cr(VI) increases in soil. The leaching test (TCLP, SPLP) could not reliably evaluate the stability effect of chromium.

Key words: chromium contaminated soil, stabilization, leaching properties, Ferrous sulfate, speciation evolution

中图分类号: 

  • TU 411.1
[1] 张亭亭, 李江山, 王平, 薛强, . FeSO4对铬污染土的稳定特性及风险评价试验研究[J]. 岩土力学, 2019, 40(10): 3928-3936.
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