岩土力学 ›› 2026, Vol. 47 ›› Issue (3): 767-779.doi: 10.16285/j.rsm.2025.0295CSTR: 32223.14.j.rsm.2025.0295

• 基础理论与实验研究 • 上一篇    下一篇

脲酶诱导碳酸钙沉积对3D打印类砂岩试样力学性能与微观结构的影响

田威1, 2,贾祎恒1,云伟1, 2,余宸1,程续1, 2   

  1. 1. 长安大学 建筑工程学院,陕西 西安 710061;2. 自然资源部退化及未利用土地整治工程重点实验室,陕西 西安 710021
  • 收稿日期:2025-03-23 接受日期:2025-04-30 出版日期:2026-03-17 发布日期:2026-03-17
  • 作者简介:田威,男,1981年生,博士,教授,博士生导师,主要从事岩土工程数值仿真、岩土材料细观力学分析方面的研究工作。E-mail: tianwei@chd.edu.cn
  • 基金资助:
    国家自然科学基金项目(No.52479115);陕西高校青年创新团队(〔2022〕943)。

Effect of enzyme-induced calcium carbonate precipitation on mechanical properties and microstructure of 3D printed sandstone-like specimens

TIAN Wei1, 2, JIA Yi-heng1, YUN Wei1, 2, YU Chen1, CHENG Xu1, 2   

  1. 1. School of Civil Engineering, Chang’an University, Xi’an, Shaanxi 710061, China; 2. Key Laboratory of Degraded and Unused Land Consolidation Engineering, Ministry of Natural Resources, Xi’an, Shaanxi 710021, China
  • Received:2025-03-23 Accepted:2025-04-30 Online:2026-03-17 Published:2026-03-17
  • Supported by:
    This work was supported by the National Natural Science Foundation of China (52479115) and the Youth Innovation Team of Shanxi Universities (〔2022〕943).

摘要: 3D打印技术在岩石室内试验中以其快速成型、复杂结构复现等优势展现出广阔应用前景,但打印试样的力学性能较差,制约了其工程实际应用。为有效提高3D打印类砂岩试样力学性能,选用GS19型砂与呋喃树脂为基材制备的类砂岩试样为对象,采用不同次数脲酶诱导碳酸钙沉积(enzyme-induced calcium carbonate precipitation,简称EICP)溶液渗透处理,通过单轴压缩试验定量分析其力学性能演化规律,并采用扫描电镜结合能谱与傅里叶变换红外光谱分析从微观尺度揭示脲酶诱导碳酸钙沉积技术的力学增强机制。结果表明:试样抗压强度与弹性模量随渗透次数递增呈现增强特性,经过4次脲酶诱导碳酸钙沉积溶液渗透处理后,试样强度较对照组提升51.92%,弹性模量提升35.57%,同时其破坏模式及裂纹扩展特征与天然弱胶结砂岩相似;从微观结构研究发现,脲酶诱导碳酸钙沉积技术促使试样内部形成“树脂−碳酸钙”复合胶结相,通过增强砂粒间胶结强度,填充孔隙降低结构缺陷的双重作用机制,试样力学性能得到显著提升。研究结果拓展了3D打印技术在岩石试验领域的应用潜力。

关键词: 岩石力学, 3D打印, 脲酶诱导碳酸钙沉积, 力学性能, 微观结构

Abstract: 3D printing technology has demonstrated broad application prospects in rock laboratory experiments due to its advantages such as rapid prototyping and complex structure reproduction. However, the poor mechanical properties of printed specimens limit their practical engineering applications. To effectively enhance the mechanical properties of 3D printed sandstone-like specimens, this study employed GS19 type sand and furan resin-based sandstone-like specimens as research objects. Specimens were treated with different cycles of enzyme-induced calcium carbonate precipitation (EICP) solution infiltration. The evolution of mechanical properties was quantitatively analyzed through uniaxial compression tests, while scanning electron microscopy-energy dispersive spectroscopy and Fourier transform infrared spectroscopy were used to reveal the mechanical enhancement mechanism of EICP technology at microscopic scale. Results indicate that the compressive strength and elastic modulus of the specimens progressively increased with infiltration cycles. After four EICP solution treatments, the specimen strength increased by 51.92% and the elastic modulus increased by 35.57% compared to the control group, with failure modes and crack propagation characteristics resembling those of natural weakly cemented sandstone. Microscopic analysis revealed that EICP technology promoted the formation of “resin-calcium carbonate” composite cementation phases within specimens. This dual mechanism of enhancing intergranular cementation strength and pore-filling to reduce structural defects significantly improved mechanical performance. The findings expand the application potential of 3D printing technology in rock experimentation.

Key words: rock mechanics, 3D printing, enzyme-induced calcium carbonate precipitation, mechanical properties, microstructure

中图分类号: TU451
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