关键词: 工业固废, 影响因素, 硅、铝、钙离子的溶出, 动力学模型, 溶解机制

Abstract: The global cement industry contributes approximately 8% of carbon dioxide emissions. Utilizing low-carbon wastes such as red mud, steel slag, and fly ash to replace cement is of great significance for carbon neutrality. To address the issue of their low reactivity in geotechnical engineering applications, this study proposes an alkaline-sulfate synergistic activation method. Techniques such as backscattered electron spectroscopy and X-ray diffraction were employed to reveal the microstructural characteristics and reaction kinetics. Experimental results indicate that the concentration of alkaline solution, temperature, dissolution time, solid-to-liquid ratio, and sulfate concentration significantly affect the dissolution of Si, Al, and Ca from the waste materials. Kinetic analysis confirms that the dissolution process follows the internal diffusion mechanism of the shrinking-core model. Among the elements, Si has a lower activation energy under alkaline conditions, resulting in higher dissolution reactivity, while Ca has a higher activation energy, making its dissolution rate more temperature-sensitive. Molecular dynamics simulations show that in the NaOH-Na2SO4 system, Si and Al exist in the form of and Al(OH)4⁻, respectively. This study provides a theoretical foundation for the development of low-carbon geotechnical materials and supports the low-carbon transformation of the construction industry.

Key words: industrial solid waste, influencing factors, leaching of silicon, aluminum, and calcium ions, kinetic model, dissolution mechanism