岩土力学 ›› 2026, Vol. 47 ›› Issue (9): 2917-2937.doi: 10.16285/j.rsm.2025.1004CSTR: 32223.14.j.rsm.2025.1004

• 基础理论与实验研究 •    下一篇

地聚合物配比对淤泥固化制备再生细骨料冲击破碎特性的影响研究

闵一凡1,幸金权1, 2, 3,赵程1, 2, 3,牛佳伦1, 2,俞松波1, 2,姜海西4   

  1. 1. 同济大学 地下建筑与工程系,上海 200092;2. 同济大学 岩土及地下工程教育部重点实验室,上海 200092; 3. 西藏大学 西藏自治区高原重大基础设施智慧建造与韧性安全技术创新中心,西藏 拉萨 850000; 4. 上海城投公路投资(集团)有限公司,上海 200335
  • 收稿日期:2025-09-17 接受日期:2025-12-24 出版日期:2026-09-11 发布日期:2026-08-28
  • 通讯作者: 幸金权,男,1997年生,博士,博士后,主要从事岩石力学与岩土体物理力学特性研究。E-mail: xingjq@tongji.edu.cn
  • 作者简介:闵一凡,男,1996年生,博士研究生,主要从事岩土固废资源化利用方面的研究。E-mail: min_yifan@tongji.edu.cn
  • 基金资助:
    国家自然科学基金项目(No.42407227);西藏自治区科技计划项目(No.XZ202501ZY013);中国博士后科学基金项目(No.2024M752423,No.GZC20241218);中央高校基本科研业务费(No.kx0020020250611)。

Influence of geopolymer proportions on the impact breakage characteristics of recycled fine aggregates produced from stabilized mud

MIN Yi-fan1, XING Jin-quan1, 2, 3, ZHAO Cheng1, 2, 3, NIU Jia-lun1, 2, YU Song-bo1, 2, JIANG Hai-xi4   

  1. 1. Department of Geotechnical Engineering, Tongji University, Shanghai 200092, China; 2. Key Laboratory of Geotechnical and Underground Engineering of Ministry of Education, Tongji University, Shanghai 200092, China; 3. Xizang Autonomous Region Plateau Major Infrastructure Intelligent Construction and Resilient Safety Technology Innovation Center, Xizang University, Lhasa, Xizang 850000, China; 4. Shanghai Chengtou Highway Group Co., Ltd., Shanghai 200335, China
  • Received:2025-09-17 Accepted:2025-12-24 Online:2026-09-11 Published:2026-08-28
  • Supported by:
    This work was supported by the National Natural Science Foundation of China (42407227), the Science and Technology Plan Project of Tibet Autonomous Region (XZ202501ZY013), China Postdoctoral Science Foundation (2024M752423, GZC20241218) and the Fundamental Research Funds for the Central Universities (kx0020020250611).

摘要: 为解决软土地区地下工程开发中的淤泥废渣问题,采用固体碱激发的矿渣−粉煤灰基地聚合物材料,对含水率为80%的淤泥进行固化处理,并将其转化为再生细骨料。首先从宏观尺度评估了先驱剂比例、掺量、固体硅酸钠模数、碱激发剂掺量及水灰比等地聚合物关键配比参数对再生细骨料的孔隙分布、连通性及颗粒堆积性能的影响,为其工程轻量化应用提供理论依据;进一步通过落锤冲击试验,分析上述配比参数对再生细骨料填料体冲击破碎特性的影响,包括冲击后的颗粒级配演化、分形维数及相对破碎指数的变化规律;最后,借助扫描电子显微镜与能量色散X射线光谱对再生细骨料单颗粒的微观形貌及化学成分进行表征,从微观尺度揭示不同地聚合物配比对再生细骨料冲击破碎特性的调控机制,并建立宏观性能与微观结构之间的跨尺度关联。研究结果表明:所有试验配比下再生细骨料填料体的堆积密度均低于1 200 kg/m3,满足防护缓冲垫层的轻质化要求。然而,不同配比的再生细骨料在基础物理性质及冲击破碎特性上表现出显著差异,这种差异主要受地聚合凝胶生成类型与孔结构形态分布控制。采用90%矿渣与10%粉煤灰组成的先驱剂(掺量为30%)、模数为0.8的固体硅酸钠及15.85%的碱激发剂掺量,以干粉混合方式直接固化含水率为80%的淤泥,可制备出基础物理性能良好且抗冲击破碎能力优异的再生细骨料。研究结果可为地下结构防护与缓冲垫层提供潜在的颗粒材料,同时有助于推动淤泥资源的高附加值利用,具有重要的工程应用价值与环境效益。

关键词: 地聚合物, 淤泥, 再生细骨料, 基础物理性质, 冲击破碎特性, 宏微观关联

Abstract: This study addresses the challenge of disposing of mud waste generated by underground engineering projects in soft-soil regions. A solid alkali-activated geopolymer based on slag and fly ash was used to stabilize mud with an initial moisture content of 80%, thereby converting it into recycled fine aggregates. First, at the macroscopic scale, this study evaluated the effects of key geopolymer mixture parameters—including precursor proportion, precursor content, the molar ratio of solid sodium silicate, alkali-activator content, and the water-to-precursor ratio—on the pore distribution, connectivity, and particle-packing behavior of the recycled fine aggregates. These findings provide a theoretical basis for their lightweight engineering application of these aggregates. Subsequently, drop-hammer impact tests were conducted to investigate how these parameters affect the impact-breakage behavior of the aggregate fills. The analysis focused on post-impact changes in particle-size distribution, fractal dimension, and relative breakage index. At the microscopic level, scanning electron microscopy and energy-dispersive X-ray spectroscopy were used to characterize the micromorphology and chemical composition of individual recycled fine-aggregate particles. These observations clarified the mechanisms governing the impact-breakage behavior of recycled fine aggregates with different mixture designs and established a cross-scale correlation between macroscopic performance and microstructure. The results show that although all trial fills satisfy the lightweight requirements for protective cushion layers (bulk density <1 200 kg/m3), their basic physical properties and impact-breakage behavior differ significantly. These differences are governed primarily by the type of geopolymer gel formed and by the morphology and spatial distribution of the pores. Notably, when the precursor contains 90% slag and 10% fly ash at a dosage of 30%, together with solid sodium silicate at a molar ratio of 0.8 and an alkali-activator content of 15.85%, direct dry mixing with mud at an initial moisture content of 80% yields recycled fine aggregates with excellent physical properties and outstanding resistance to impact breakage. The findings of this study identify a promising granular material for the protective cushion layers of underground structures. They also promote the high-value utilization of mud resources and demonstrate significant engineering and environmental benefits.

Key words: geopolymer, mud, recycled fine aggregate, basic physical properties, impact-breakage characteristics, macro–micro correlations

中图分类号: TU521
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