The
modified fibers exhibit excellent heavy metal adsorption capacity and
mechanical strength, offering broad application potential in the remediation of
contaminated soil. Jute was used as a fiber material, which was modified by
pyromellitic dianhydride, polyaniline and hydrogen peroxide respectively. The
study examined the solidification efficiency of modified jute fiber in
conjunction with cement, utilizing indicators such as unconfined compressive
strength, cation exchange capacity (CEC), electrical conductivity (EC), and pH
value. Additionally, the toxicological evolution of this material was analyzed
using the acetic acid buffer solution method. The results indicate that the
optimal combination of modified jute fiber and cement co-solidification
effectively enhances strength and mitigates toxicity release. The unconfined
compressive strength of the co-solidified contaminated soil exceeds that of
cement-only solidification by 76.78%. Furthermore, the leaching toxicity and
its fluctuation under 10 freeze-thaw cycles are reduced by 64.73% and to one-third
of the original level. The hydrolysis of jute produces alkaline cellulose,
which effectively elevates the pH of cement-solidified contaminated soil. The
modification of carboxyl acid functional groups promotes hydration reactions
via neutralization, thereby enhancing the formation of calcium silicate hydrate
(CSH). The introduction of jute, especially modified fibers, significantly
improves the EC and CEC. Under the co-solidified function of fiber and cement,
the increase of EC can reach 2.25 times that of cement-only solidification,
which is the key to enhance the stability of adsorption. However, due to the
influence of fiber agglomeration, particle polymerization, and electrostatic
repulsion between metal ions, the strength and leaching toxicity of solidified
contaminated soil are not positively correlated with fiber dosage and length.
Among the three modification methods, the jute fiber modified with pyromellitic
anhydride exhibits a robust adsorption and solidification effect, which is
minimally influenced by fiber length and dosage. Furthermore, it demonstrates
superior performance in terms of strength and toxicity control indicators. Considering
both engineering applications and ecological development requirements,
pyromellitic dianhydride-modified jute fiber (with a dosage of 0.9% and a fiber
length of 18 mm) is more suitable for enhancing the effectiveness of cement in
treating heavy metal-contaminated soil.