岩土力学 ›› 2021, Vol. 42 ›› Issue (1): 104-112.doi: 10.16285/j.rsm.2020.0442

• 基础理论与实验研究 • 上一篇    下一篇

石灰-红黏土互损行为与偏高岭土减损机制

谈云志1,占少虎1,胡焱1,曹玲1,邓永锋2,明华军1,沈克军3   

  1. 1. 三峡大学 特殊土资源化利用宜昌市重点实验室,湖北 宜昌 443002;2. 东南大学 岩土工程研究所,江苏 南京 211189; 3. 宜昌鸿乾环保建材有限公司,湖北 宜昌 443100
  • 收稿日期:2020-04-15 修回日期:2020-10-26 出版日期:2021-01-11 发布日期:2021-01-06
  • 作者简介:谈云志,男,1979年生,博士,教授,主要从事特殊土方面的教学与科研工作
  • 基金资助:
    国家自然科学基金项目(No. 51579137);湖北省优秀中青年科技创新团队计划项目(No. T201803)

Behavior of lime-laterite interaction and anti-erosion mechanism of Metakaolin

TAN Yun-zhi1, ZHAN Shao-hu1, HU Yan1, CAO Ling1, DENG Yong-feng2, MING Hua-jun1, SHEN Ke-jun3   

  1. 1. Yichang Key Laboratory of the Resources Utilization for Problematic Soils, China Three Gorges University, Yichang, Hubei 443002, China; 2. Institute of Geotechnical Engineering, Southeast University, Nanjing, Jiangsu 211189, China; 3. Yichang Hongqian Environmental Building Materials Co. Ltd., Yichang, Hubei 443100, China
  • Received:2020-04-15 Revised:2020-10-26 Online:2021-01-11 Published:2021-01-06
  • Supported by:
    This work was supported by the National Natural Science Foundation of China (51579137) and the Youth Innovation Team Project of Hubei Province (T201803).

摘要: 红黏土成团现象突出,导致石灰处治红黏土时难以拌和均匀;同时,红黏土呈弱酸性,石灰与黏土会发生互损作用,最终影响处治效果。首先,从水分子与黏土矿物的电荷分布特征角度,解释了红黏土呈弱酸性的原因;然后,通过酸、碱溶液浸泡石灰处治红黏土,模拟石灰?红黏土的互损行为;最后,提出应用偏高岭土抑制“石灰?红黏土”互损的方法。为此,选择两种团粒尺寸的红黏土,掺入不同比例的偏高岭土和石灰,并评价其无侧限抗压强度。结果表明,与仅用石灰处治的红黏土相比,掺入偏高岭土过多或过少都不利于其强度提高,掺量为5%效果最佳,验证了偏高岭土抑制“石灰?红黏土”互损行为的可行性。偏高岭土与石灰快速反应,不仅生成了以离子键结合的硅、铝酸胶结物,还生成了以共价键结合的网状胶结物,而且后者具有明显的抗酸侵蚀能力,从而解释了偏高岭土能够减少石灰?红黏土互损的内在原因。

关键词: 偏高岭土, 石灰, 团粒尺寸, 红黏土, 强度

Abstract: Laterite is prone to form as aggregate due to its high clay content, leading to a difficultly in uniformly mixing itwith lime. Meanwhile, is the weak acid property of laterite promotes the interaction between the lime and laterite, which shows a significant influence on the final treatment effects. In this paper, the causes of the weak acidity of laterite are firstly studied through the charges distribution characteristics of water molecules and clay minerals. Then, the interaction between lime and laterite is simulated through soaking the lime-treated laterite in the acid and alkaline solution respectively. Based on the results, the method to inhibit the lime-laterite interaction by metakaolin is proposed. Laterite with two groups size, mixed with different dose of metakaolin and lime are adopted to conduct the unconfined compressive strength tests. The results show that compared with the laterite treated with lime alone, neither excessive nor insufficient metakaolin has contribution to its strength improvement, and the best treatment effect can be obtained with the dose of 5.0% metakaolin, which verifies the feasibility of metakaolin to inhibit the lime-laterite interaction . Reactions between metakaolin and limecan form not only the silicon and aluminate cementation bonded by ionic bond but also the reticular cementation bonded by covalent bond. Since the latter has a significant ability toresist erosion by acid, the internal reason of lime-laterite interaction undermined by metakaolin is interpreted.

Key words: metakaolin, lime, aggregate size, laterite, strength

中图分类号: TU 411
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